Critical Behavior of Linear Polymer Chains Adsorbed Onto Surfaces


Semiflexible chains - Adsorption

Block copolymers - Adsorption
      

The equilibrium phase transitions and scaling laws governing the critical adsorption of linear polymer chains onto attractive solid boundaries are examined. Performing highly efficient Monte Carlo and Molecular Dynamics simulations, this work systematically maps phase diagrams and reveals how critical boundary behavior is governed by chain characteristics such as stiffness and monomer sequence, and the surface potential.




"Effect of Chain Stiffness on the Adsorption Transition of Polymers", Macromolecules 46, 2496 (2013).



"Adsorption of Multi-block and Random Copolymer on a Solid Surface: Critical Behavior and Phase Diagram", Macromolecules, 41, 2920 (2008).